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Pushing the glass transition towards random close packing using self-propelled hard spheres

机译:使用玻璃将玻璃过渡推向随机密堆积   自行式硬球

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摘要

Although the concept of random close packing with an almost universal packingfraction of ~ 0.64 for hard spheres was introduced more than half a centuryago, there are still ongoing debates. The main difficulty in searching thedensest packing is that states with packing fractions beyond the glasstransition at ~ 0.58 are inherently non-equilibrium systems, where the dynamicsslows down with a structural relaxation time diverging with density; hence, therandom close packing is inaccessible. Here we perform simulations ofself-propelled hard spheres, and we find that with increasing activity therelaxation dynamics can be sped up by orders of magnitude. The glass transitionshifts to higher packing fractions upon increasing the activity, allowing thestudy of sphere packings with fluid-like dynamics at packing fractions close torandom close packing. Our study opens new possibilities of investigating densepackings and the glass transition in systems of hard particles.
机译:尽管在半个多世纪前就引入了对于硬球几乎为0.64的普遍密堆积分数的随机紧密堆积的概念,但仍存在争论。寻找最稠密堆积的主要困难是,堆积分数超出玻璃化转变点(约0.58)的状态本质上是非平衡系统,其中动力学会降低,结构弛豫时间随密度而变化。因此,无法进行随机密密的包装。在这里,我们对自我推进的硬球体进行了模拟,发现随着活动的增加,松弛的动力学可以加快几个数量级。随着活性的增加,玻璃化转变转变为更高的填充率,从而使球形填充物的研究在填充率接近无规紧密填充时具有类似流体的动力学。我们的研究为研究硬颗粒系统中的致密堆积和玻璃化转变提供了新的可能性。

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